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Silicon, a tetravalent metalloid is a chemical element with the symbol Si and atomic number 14. It is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive thangermanium, the metalloid directly below it in the table. Controversy about silicon's character dates to its discovery; it was first prepared and characterized in pure form in 1823. HP Pavilion dv7-1157cl CPU Fan 

In 1808, it was given the name silicium (from Latin:silex, hard stone or flint), with an -ium word-ending to suggest a metal, a name which the element retains in several non-English languages. However, its final English name, first suggested in 1817, reflects the more physically similar elements carbon and boron.

Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure free element in nature. HP Pavilion dv6-3163eo CPU Fan

It is most widely distributed in dusts, sands, planetoids, and planets as various forms of silicon dioxide(silica) or silicates. Over 90% of the Earth's crust is composed of silicate minerals, making silicon the second most abundant element in the Earth's crust (about 28% by mass) after oxygen.[7]

Most silicon is used commercially without being separated, and indeed often with little processing of compounds from nature. HP Pavilion dv9740us CPU Fan

These include direct industrial building-use of clays, silica sand and stone. Silica is used in ceramic brick. Silicate goes into Portland cement for mortar and stucco, and when combined with silica sand and gravel, to makeconcrete. Silicates are also in whiteware ceramics such as porcelain, and in traditional quartz-based soda-lime glass. More modern silicon compounds such as silicon carbide form abrasives and high-strength ceramics. HP COMPAQ NX9420 CPU Fan

Silicon is the basis of the ubiquitous synthetic silicon-based polymers called silicones.

Elemental silicon also has a large impact on the modern world economy. Although most free silicon is used in the steelrefining, aluminum-casting, and fine chemical industries (often to make fumed silica), the relatively small portion of very highly purified silicon that is used in semiconductor electronics (< 10%) is perhaps even more critical. HP Pavilion dv7-4150ec CPU Fan

Because of wide use of silicon in integrated circuits, the basis of most computers, a great deal of modern technology depends on it.

Silicon is an essential element in biology, although only tiny traces of it appear to be required by animals.[8]However, various sea sponges as well as microorganisms like diatoms need silicon in order to have structure. It is much more important to the metabolism of plants, particularly many grasses. HP Pavilion dv5-1102tu CPU Fan

Silicon is a solid at room temperature, with relatively high melting and boiling points of 1414 and 3265 degrees Celsius respectively. It has a greater density in a liquid state than a solid state. It does not contract when it freezes like most substances, but expands, similar to how ice is less dense than water. With a relatively high thermal conductivity of 149 W·m−1·K−1SONY VGN-SZ220 CPU Fan

silicon conducts heat well and as a result is not often used to insulate hot objects.

In its crystalline form, pure silicon has a gray color and a metallic luster. Likegermanium, silicon is rather strong, very brittle, and prone to chipping. Silicon, like carbon and germanium, crystallizes in a diamond cubic crystal structure, with a lattice spacing of 0.5430710 nm (5.430710 Å).[9] HP Pavilion dv7-6011tx CPU Fan

The outer electron orbital of silicon, like that of carbon, has four valence electrons. The 1s, 2s, 2p and 3s subshells are completely filled while the 3p subshell contains two electrons out of a possible six.

Silicon is a semiconductor. It has a negative temperature coefficient of resistance, since the number of free charge carriers increases with temperature. HP Pavilion dv5-1040eb CPU Fan

The electrical resistance of single crystal silicon significantly changes under the application of mechanical stress due to the piezoresistive effect.

Silicon is a metalloid, readily either donating or sharing its four outer electrons, allowing for many forms of chemical bonding. Like carbon, it typically forms four bonds. Unlike carbon, it can accept additional electrons and form five or six bonds in a sometimes more labile silicate form. ASUS F3Jv CPU Fan

Tetra-valent silicon is relatively inert, but still reacts withhalogens and dilute alkalis, but most acids (except for some hyper-reactive combinations ofnitric acid and hydrofluoric acid) have no known effect on it. However, having four bonding electrons gives it, like carbon, many opportunities to combine with other elements or compounds under the right circumstances. IBM ThinkPad R50p 2887 CPU Fan

Naturally occurring silicon is composed of three stable isotopes, silicon-28, silicon-29, and silicon-30, with silicon-28 being the most abundant (92% natural abundance).[11] Out of these, only silicon-29 is of use in NMR and EPR spectroscopy.[12] Twenty radioisotopes have been characterized, with the most stable being silicon-32 with a half-lifeof 170 years, and silicon-31 with a half-life of 157.3 minutes.[11] SONY VGN-CS36GJ/R CPU Fan

All of the remaining radioactive isotopes have half-lives that are less than seven seconds, and the majority of these have half-lives that are less than one tenth of a second.[11] Silicon does not have any known nuclear isomers.[11]

The isotopes of silicon range in mass number from 22 to 44.[11] The most common decay mode of six isotopes with mass numbers lower than the most abundant stable isotope, silicon-28, is β+, primarily forming aluminium isotopes (13 protons) as decay products.[11] Toshiba Satellite A215-S4807 CPU Fan

The most common decay mode(s) for 16 isotopes with mass numbers higher than silicon-28 is β−, primarily forming phosphorus isotopes (15 protons) as decay products.

Measured by mass, silicon makes up 27.7% of the Earth's crust and is the second most abundant element in the crust, with only oxygen having a greater abundance.[13] Toshiba Satellite Pro M10-SP405 CPU Fan

Silicon is usually found in the form of complex silicate minerals, and less often as silicon dioxide(silica, a major component of common sand). Pure silicon crystals are very rarely found in nature.

The silicate minerals—various minerals containing silicon, oxygen and reactive metals—account for 90% of the mass of the Earth's crust. HP Pavilion dv4-1120us CPU Fan

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This is due to the fact that at the high temperatures characteristic of the formation of the inner solar system, silicon and oxygen have a great affinity for each other, forming networks of silicon and oxygen in chemical compounds of very low volatility. Since oxygen and silicon were the most common non-gaseous and non-metallic elements in the debris from supernova dust which formed the protoplanetary disk in the formation and evolution of the Solar System, Toshiba Qosmio E15-AV101 CPU Fan

they formed many complex silicates which accreted into larger rocky planetesimals that formed the terrestrial planets. Here, the reduced silicate mineral matrix entrapped the metals reactive enough to be oxidized (aluminum, calcium, sodium, potassium and magnesium). After loss of volatile gases, as well as carbon and sulfur via reaction with hydrogen, this silicate mixture of elements formed most of the Earth's crust. Toshiba Satellite L645D-S4056 CPU Fan

These silicates were of relatively low density with respect to iron, nickel, and other metals non-reactive to oxygen and thus a residuum of uncombined iron and nickel sank to the planet's core, leaving a thick mantle consisting mostly of magnesium and iron silicates. These are thought to be mostly silicate perovskites, followed in abundance by the magnesium/iron oxide ferropericlase.[14] Toshiba Satellite A305-S6837 CPU Fan

Examples of silicate minerals in the crust include those in the pyroxene, amphibole, mica, and feldspar groups. These minerals occur in clay and various types of rock such as granite and sandstone.

Silica occurs in minerals consisting of very pure silicon dioxide in different crystalline forms, quartz, agateamethyst, rock crystal, chalcedony, flint, jasper, and opal. HP Pavilion dv7-4087cl CPU Fan

The crystals have the empirical formula of silicon dioxide, but do not consist of separate silicon dioxide molecules in the manner of solid carbon dioxide. Rather, silica is structurally a network-solid consisting of silicon and oxygen in three-dimensional crystals, like diamond. Less pure silica forms the natural glass obsidian. Biogenic silica occurs in the structure of diatoms, radiolaria and siliceous sponges. HP Pavilion dv5-1118es CPU Fan

Silicon is also a principal component of many meteorites, and is a component of tektites, a silicate mineral of possibly lunar origin, or (if Earth-derived) which has been subjected to unusual temperatures and pressures, possibly from meteorite strike.

Ferrosilicon, an iron-silicon alloy that contains varying ratios of elemental silicon and iron, Toshiba Satellite A665-S6050 CPU Fan

accounts for about 80% of the world's production of elemental silicon, with China, the leading supplier of elemental silicon, providing 4.6 million tonnes (or 2/3 of the world output) of silicon, most of which is in the form of ferrosilicon. It is followed by Russia (610,000 t), Norway (330,000 t), Brazil (240,000 t) and the United States (170,000 t).[15] Ferrosilicon is primarily used by the steel industry (see below). HP Pavilion G72-259WM CPU Fan

Aluminum-silicon alloys are heavily used in the aluminum alloy casting industry, where silicon is the single most important additive to aluminum to improve its casting properties. Since cast aluminum is widely used in the automobile industry, this use of silicon is thus the single largest industrial use of "metallurgical grade" pure silicon (as this purified silicon is added to pure aluminum, whereas ferrosilicon is never purified before being added to steel). HP Pavilion dv6-3109ca  CPU  Fan

Elemental silicon not alloyed with significant quantities of other elements, and usually > 95%, is often referred to loosely as silicon metal. It makes up about 20% of the world total elemental silicon production, with less than 1 to 2% of total elemental silicon (5–10% of metallurgical grade silicon) ever purified to higher grades for use in electronics. HP Pavilion dv6782eg CPU Fan

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Metallurgical grade silicon is commercially prepared by the reaction of high-purity silica with wood, charcoal, and coal in an electric arc furnace using carbon electrodes. At temperatures over 1,900 °C (3,450 °F), the carbon in the aforementioned materials and the silicon undergo the chemical reaction SiO2 + 2 C → Si + 2 CO. Liquid silicon collects in the bottom of the furnace, which is then drained and cooled. Toshiba UDQFRPH33CCM CPU Fan

The silicon produced in this manner is called metallurgical grade silicon and is at least 98% pure. Using this method, silicon carbide (SiC) may also form from an excess of carbon in one or both of the following ways: SiO2 + C → SiO + CO or SiO + 2 C → SiC + CO. However, provided the concentration of SiO2 is kept high, the silicon carbide can be eliminated by the chemical reaction 2 SiC + SiO2 → 3 Si + 2 CO. Toshiba Satellite A505-S6980 CPU Fan

As noted above, metallurgical grade silicon "metal" has its primary use in the aluminum casting industry to make aluminum-silicon alloy parts. The remainder (about 45%) is used by the chemical industry, where it is primarily employed to make fumed silica.[17]

As of September 2008, metallurgical grade silicon costs about US$1.45 per pound ($3.20/kg),[18] up from $0.77 per pound ($1.70/kg) in 2005. HP Pavilion dv7-2025es CPU Fan

The use of silicon in semiconductor devices demands a much greater purity than afforded by metallurgical grade silicon. Very pure silicon (>99.9%) can be extracted directly from solid silica or other silicon compounds by molten salt electrolysis.[20][21] This method, known as early as 1854[22] (see also FFC Cambridge process), has the potential to directly produce solar-grade silicon without any carbon dioxide emission at much lower energy consumption. TOSHIBA Satellite L300 CPU Fan

Solar grade silicon cannot be used for semiconductors, where purity must be extreme to properly control the process. Bulk silicon wafers used at the beginning of the integrated circuit making process must first be refined to "nine nines" purity (99.9999999%), a process which requires repeated applications of refining technology.

The majority of silicon crystals grown for device production are produced by the Czochralski process, HP G62-a10EJ CPU Fan

(CZ-Si) since it is the cheapest method available and it is capable of producing large size crystals. However, single crystals grown by the Czochralski process contain impurities because the crucible containing the melt often dissolves. Historically, a number of methods have been used to produce ultra-high-purity silicon.

Early silicon purification techniques were based on the fact that if silicon is melted and re-solidified, the last parts of the mass to solidify contain most of the impurities. Dell MF60100V1-Q000-G99 CPU Fan

The earliest method of silicon purification, first described in 1919 and used on a limited basis to make radar components during World War II, involved crushing metallurgical grade silicon and then partially dissolving the silicon powder in an acid. When crushed, the silicon cracked so that the weaker impurity-rich regions were on the outside of the resulting grains of silicon.DELL R859C CPU Fan

As a result, the impurity-rich silicon was the first to be dissolved when treated with acid, leaving behind a more pure product.In zone melting, also called zone refining, the first silicon purification method to be widely used industrially, rods of metallurgical grade silicon are heated to melt at one end. Then, the heater is slowly moved down the length of the rod, keeping a small length of the rod molten as the silicon cools and re-solidifies behind it. SONY Vaio VGN-FW140E CPU Fan

Since most impurities tend to remain in the molten region rather than re-solidify, when the process is complete, most of the impurities in the rod will have been moved into the end that was the last to be melted. This end is then cut off and discarded, and the process repeated if a still higher purity is desired.

At one time, DuPont produced ultra-pure silicon by reacting silicon tetrachloride with high-purity zincvapors at 950 °C, producing silicon by SiCl4 + 2 Zn → Si + 2 ZnCl2ACER Aspire 5730Z CPU Fan

However, this technique was plagued with practical problems (such as the zinc chloride byproduct solidifying and clogging lines) and was eventually abandoned in favor of the Siemens process. In the Siemens process, high-purity silicon rods are exposed to trichlorosilane at 1150 °C. The trichlorosilane gas decomposes and deposits additional silicon onto the rods, enlarging them because 2 HSiCl3 → Si + 2 HCl + SiCl4SONY Vaio VPC-EB4S1E/WI CPU Fan

Silicon produced from this and similar processes is called polycrystalline silicon. Polycrystalline silicon typically has impurity levels of less than one part per billion.[24][25][26]

In 2006 REC announced construction of a plant based on fluidized bed (FB) technology using silane: 3 SiCl4 + Si + 2 H2 → 4 HSiCl3, 4 HSiCl3 → 3 SiCl4 + SiH4, SiH4 → Si + 2 H2.[27] HP Pavilion dv9580ed CPU Fan

The advantage of fluid bed technology is that processes can be run continuously, yielding higher yields than Siemens Process, which is a batch process.

Today, silicon is purified by converting it to a silicon compound that can be more easily purified by distillation than in its original state, and then converting that silicon compound back into pure silicon. Toshiba Satellite L305D-S5934 CPU Fan

Trichlorosilane is the silicon compound most commonly used as the intermediate, although silicon tetrachloride and silane are also used. When these gases are blown over silicon at high temperature, they decompose to high-purity silicon.

In addition, there is the Schumacher process, which utilizes tribromosilane in place of trichlorosilane and fluid bed technology.SONY Vaio VGN-CR31S/P CPU Fan

It requires lower deposition temperatures, lower capital costs to build facilities and operate, no hazardous polymers nor explosive material, and produces no amorphous silicon dust waste, all of which are drawbacks of the Siemens process.[28] However, there are yet to be any major factories built using this process. HP Pavilion dv5-1210et CPU Fan

  • Silicon forms binary compounds called silicides with many metallic elements whose properties range from reactive compounds, e.g.magnesium silicide, Mg2Si through high melting refractory compounds such as molybdenum disilicide, MoSi2.[29]

Silicon carbide, SiC (carborundum) is a hard, high melting solid and a well known abrasive. It may also be sintered into a type of high-strength ceramic used in armor. SONY Vaio VGN-FW465J/B CPU Fan

Silane, SiH4, is a pyrophoric gas with a similar tetrahedral structure to methane, CH4. When pure, it does not react with pure water or dilute acids; however, even small amounts of alkali impurities from the laboratory glass can result in a rapid hydrolysis.[30] There is a range of catenated silicon hydrides that form a homologous series of compounds, SinH2n+2 where n = 2–8 (analogous to the alkanes). HP Envy 15 CPU Fan

  • These are all readily hydrolyzed and are thermally unstable, particularly the heavier members.[31][32]

Disilenes contain a silicon-silicon double bond (analogous to the alkenes) and are generally highly reactive requiring large substituent groups to stabilize them.[33] A disilyne with a silicon-silicon triple bond was first isolated in 2004; although as the compound is non-linear, the bonding is dissimilar to that in alkynes.[34] HP Pavilion dv7-1190er CPU Fan

Tetrahalides, SiX4, are formed with all the halogens.[35] Silicon tetrachloride, for example, reacts with water, unlike its carbon analogue, carbon tetrachloride.[36] Silicon dihalides are formed by the high temperature reaction of tetrahalides and silicon; with a structure analogous to a carbene they are reactive compounds. Silicon difluoride condenses to form a polymeric compound, (SiF2)n.[32] Toshiba Satellite A105-S4074 CPU Fan

Silicon dioxide is a high melting solid with a number of crystal forms; the most familiar of which is the mineral quartz. In quartz each silicon atom is surrounded by four oxygen atoms that bridge to other silicon atoms to form a three dimensional lattice.[36] Silica is soluble in water at high temperatures forming a range of compounds called monosilicic acid, Si(OH)4.[37]  IBM MCF-208AM05-1 CPU Fan

Under the right conditions monosilicic acid readily polymerizes to form more complex silicic acids, ranging from the simplest condensate, disilicic acid (H6Si2O7) to linear, ribbon, layer and lattice structures which form the basis of the many silicate minerals and are called polysilicic acids {Six(OH)4–2x}n.[37]

With oxides of other elements the high temperature reaction of silicon dioxide can give a wide range of glasses with various properties.[38] IBM MCF-217PAM05 CPU Fan

  • Examples include soda lime glass, borosilicate glass and lead crystal glass.
  • Silicon sulfide, SiS2, is a polymeric solid (unlike its carbon analogue the liquid CS2).[39]

Silicon forms a nitride, Si3N4 which is a ceramic.[40] Silatranes, a group of tricyclic compounds containing five-coordinate silicon, may have physiological properties.[41]  HP GB0507PGV1-A CPU Fan

  • Many transition metal complexes containing a metal-silicon bond are now known, which include complexes containing SiH
    nX
    3−n ligands, SiX3 ligands, and Si(OR)3ligands.[41]

Silicones are large group of polymeric compounds with an (Si-O-Si) backbone. An example is the silicone oil PDMS (polydimethylsiloxane). IBM MCF-217PAM05 CPU Fan

These polymers can be crosslinked to produce resins and elastomers.[42]

Many organosilicon compounds are known which contain a silicon-carbon single bond. Many of these are based on a central tetrahedral silicon atom, and some are optically active when central chirality exists. Long chain polymers containing a silicon backbone are known, such as polydimethysilylene (SiMe
2)n.[43] HP Pavilion dv6-3385la CPU Fan

Polycarbosilane, [(SiMe2)2CH2]n with a backbone containing a repeating -Si-Si-C unit, is a precursor in the production of silicon carbide fibers.

Attention was first drawn to silica as the possible oxide of a fundamental chemical element by Antoine Lavoisier, in 1787.[44] After an attempt to isolate silicon in 1808, Sir Humphry Davy proposed the name "silicium" for silicon, from the Latin silexsilicis for flint, flints, and adding the "-ium" ending because he believed it was a metal.[45] HP Pavilion tx2510us  CPU  Fan

In 1811, Gay-Lussac and Thénard are thought to have prepared impure amorphous silicon, through the heating of recently isolated potassium metal with silicon tetrafluoride, but they did not purify and characterize the product, nor identify it as a new element.[46] Silicon was given its present name in 1817 by Scottish chemist Thomas Thomson. HP G62-b55EV CPU Fan

He retained part of Davy's name but added "-on" because he believed that silicon was anonmetal similar to boron and carbon.[47] In 1823, Berzelius prepared amorphous silicon using approximately the same method as Gay-Lussac (potassium metal and potassium fluorosilicate), but purifying the product to a brown powder by repeatedly washing it.[48] As a result he is usually given credit for the element's discovery.[49][50] HP Pavilion dv6-2145sf CPU Fan

Silicon in its more common crystalline form was not prepared until 31 years later, by Deville.[51][52] By electrolyzing impure sodium-aluminum chloridecontaining approximately 10% silicon, he was able to obtain a slightly impure allotrope of silicon in 1854.[53] Later, more cost-effective methods have been developed to isolate silicon in several allotrope forms, the most recent being silicene. HP Pavilion dv7-1120ew CPU Fan

Because silicon is an important element in semiconductors and high-technology devices, many places in the world bear its name. For example, Silicon Valley inCalifornia, since it is the base for a number of technology-related industries, bears the name silicon. Other geographic locations with connections to the industry have since been named after silicon as well. HP 538340-001 CPU Fan

Examples include Silicon Forest in Oregon, Silicon Hills in Austin, Texas, Silicon Saxony in Germany,Silicon Valley in India, Silicon Border in Mexicali, Mexico, Silicon Fen in Cambridge, England, Silicon Roundabout in London, Silicon Glen in Scotland, andSilicon Gorge in Bristol, England.

Most silicon is used industrially without being separated into the element, and indeed often with comparatively little processing from natural occurrence. HP 535766-001 CPU Fan

Over 90% of the Earth's crust is composed of silicate minerals. Many of these have direct commercial uses, such as clays, silica sand and most kinds of building stone. Thus, the vast majority of uses for silicon are as structural compounds, either as the silicate minerals or silica (crude silicon dioxide). For example, silica is an important part of ceramic brick. HP 535442-001 CPU Fan

Silicates are used in making Portland cement which is used in building mortar and stucco, but more importantly combined with silica sand, and gravel (usually containing silicate minerals like granite), to make the concrete that is the basis of most of the very largest industrial building projects of the modern world. [54] HP 535441-001 CPU Fan

Silicate minerals are also in whiteware ceramics, an important class of products usually containing various types of fired clay (natural aluminum silicate). An example is porcelain which is based on silicate mineral kaolinite. Ceramics include art objects, and domestic, industrial and building products. Traditional quartz-based soda-lime glass also functions in many of the same roles.HP 535439-001 CPU Fan

More modern silicon compounds also function as high-technology abrasives and new high-strength ceramics based upon (silicon carbide), and in superalloys.

Alternating silicon-oxygen chains with hydrogen attached to the remaining silicon bonds form the ubiquitous silicon-based polymeric materials known assilicones. HP 535438-001 CPU Fan

These compounds containing silicon-oxygen and occasionally silicon-carbon bonds have the capability to act as bonding intermediates between glass and organic compounds, and to form polymers with useful properties such as impermeability to water, flexibility and resistance to chemical attack. HP 533736-001 CPU Fan

Silicones are often used in waterproofing treatments, molding compounds, mold-release agents, mechanical seals, high temperature greases and waxes, and caulking compounds. Silicone is also sometimes used in breast implants, contact lenses, explosives and pyrotechnics.[55] Silly Putty was originally made by adding boric acid tosilicone oil. IBM 13R2760 CPU Fan

Elemental silicon is added to molten cast iron as ferrosilicon or silicocalcium alloys to improve performance in casting thin sections and to prevent the formation of cementite where exposed to outside air. The presence of elemental silicon in molten iron acts as a sink for oxygen, so that the steel carbon content, which must be kept within narrow limits for each type of steel, can be more closely controlled. ACER LU.S040A.067 CPU Fan

Ferrosilicon production and use is a monitor of the steel industry, and although this form of elemental silicon is impure, it accounts for 80% of the world's use of free silicon.

The properties of silicon itself can be used to modify alloys. Silicon's importance in aluminum casting is that a significantly high amount (12%) of silicon in aluminum forms a eutectic mixture which solidifies with very little thermal contraction. ACER LU.S050B.078 CPU Fan

This greatly reduces tearing and cracks formed from stress as casting alloys cool to solidity. Silicon also significantly improves the hardness and thus wear-resistance of aluminum.[16] Silicon is an important constituent ofelectrical steel, modifying its resistivity and ferromagnetic properties.

Metallurgical grade silicon is silicon of 95–99% purity. DELL Studio 1535 CPU Fan

About 55% of the world consumption of metallurgical purity silicon goes for production of aluminum-silicon alloys for aluminum part casts, mainly for use in the automotive industry. The reason for the high silicon use in these alloys is noted above.[17] Much of the rest of metallurgical-grade silicon is used by the chemical industry for production of the important industrial product fumed silica. HP Pavilion dv6736nr CPU Fan

The remainder is used in production of other fine chemicals such as silanes and some types of silicones.

Since most elemental silicon produced remains as ferrosilicon alloy, only a relatively small amount (20%) of the elemental silicon produced is refined to metallurgical grade purity (a total of 1.3–1.5 million metric tons/year). HP Envy 15-1050ca CPU Fan

The fraction of silicon metal which is further refined to semiconductor purity is estimated at only 15% of the world production of metallurgical grade silicon.[17]However, the economic importance of this small very high-purity fraction (especially the ~ 5% which is processed to monocrystalline silicon for use in integrated circuits) is disproportionately large. HP Pavilion dv7-6100et CPU Fan

Pure monocrystalline silicon is used to produce silicon wafers used in the semiconductor industry, in electronics and in some high-cost and high-efficiency photovoltaic applications. In terms of charge conduction, pure silicon is an intrinsic semiconductor which means that unlike metals it conducts electron holes and electrons that may be released from atoms within the crystal by heat, APPLE 661-4951 CPU Fan

and thus increase silicon's electrical conductivity with higher temperatures. Pure silicon has too low a conductivity (i.e., too high aresistivity) to be used as a circuit element in electronics. In practice, pure silicon is doped with small concentrations of certain other elements, a process that greatly increases its conductivity and adjusts its electrical response by controlling the number and charge (positive or negative) of activated carriers. IBM 42W2403 CPU Fan

Such control is necessary for transistors, solar cells, semiconductor detectorsand other semiconductor devices, which are used in the computer industry and other technical applications. For example, in silicon photonics, silicon can be used as a continuous wave Raman laser medium to produce coherent light, though it is ineffective as an everyday light source. ACER Aspire 9304WSMi CPU Fan

In common integrated circuits, a wafer of monocrystalline silicon serves as a mechanical support for the circuits, which are created by doping, and insulated from each other by thin layers of silicon oxide, an insulator that is easily produced by exposing the element to oxygen under the proper conditions. Silicon has become the most popular material to build both high power semiconductors and integrated circuits. HP 610773-001 CPU Fan

The reason is that silicon is the semiconductor that can withstand the highest temperatures and electrical powers without becoming dysfunctional due to avalanche breakdown (a process in which an electron avalanche is created by a chain reaction process whereby heat produces free electrons and holes, which in turn produce more current which produces more heat). IBM ThinkPad R50p 1830 CPU Fan

In addition, the insulating oxide of silicon is not soluble in water, which gives it an advantage over germanium (an element with similar properties which can also be used in semiconductor devices) in certain type of fabrication techniques.[57]

Monocrystalline silicon is expensive to produce, and is usually only justified in production of integrated circuits, where tiny crystal imperfections can interfere with tiny circuit paths. IBM ThinkPad T61 8898 CPU Fan

For other uses, other types of pure silicon which do not exist as single crystals may be employed. These include hydrogenated amorphous silicon and upgraded metallurgical-grade silicon (UMG-Si) which are used in the production of low-cost, large-area electronics in applications such asliquid crystal displays, and of large-area, low-cost, thin-film solar cells. IBM ThinkPad R50p 2889 CPU Fan

Such semiconductor grades of silicon which are either slightly less pure than those used in integrated circuits, or which are produced in polycrystalline rather than monocrystalline form, make up roughly similar amount of silicon as are produced for the monocrystalline silicon semiconductor industry, or 75,000 to 150,000 metric tons per year. IBM ThinkPad R50p 1830 CPU Fan

However, production of such materials is growing more quickly than silicon for the integrated circuit market. By 2013 polycrystalline silicon production, used mostly in solar cells, is projected to reach 200,000 metric tons per year, while monocrystalline semiconductor silicon production (used in computer microchips) remains below 50,000 tons/year. IBM ThinkPad R50 1829 CPU Fan

Although silicon is readily available in the form of silicates, very few organisms have a use for it. Diatoms, radiolaria andsiliceous sponges use biogenic silica as a structural material to construct skeletons. In more advanced plants, the silicaphytoliths (opal phytoliths) are rigid microscopic bodies occurring in the cell; some plants, for example rice, need silicon for their growth.[58][59][60] IBM ThinkPad R50P CPU Fan

Although silicon was proposed to be an ultra trace nutrient, its exact function in the biology of animals is still under discussion. Higher organisms are only known to use it in very limited occasions in the form ofsilicic acid and soluble silicates.[citation needed]

Silicon is known to be needed for synthesis of elastin and collagen; the aorta contains the highest quantity of elastin and silicon.[61] IBM Thinkpad W500 CPU Fan

Silicon is currently under consideration for elevation to the status of a "plant beneficial substance by the Association of American Plant Food Control Officials (AAPFCO)."[62][63] Silicon has been shown in university and field studies to improve plant cell wall strength and structural integrity,[64] improve drought and frost resistance, decrease lodging potential and boost the plant's natural pest and disease fighting systems.[65] Silicon has also been shown to improve plant vigor and physiology by improving root mass and density, and increasing above ground plant biomass and crop yields.[64] Compaq Presario CQ41-206TU CPU Fan

Hypothetical silicon-based lifeforms are the subject of silicon biochemistry, by analogy with carbon-based lifeforms. Silicon, being below carbon in the periodic table, is thought to have similar enough properties that would make silicon-based life possible, but much different from life as we know it.

Amorphous silicon (a-Si) is the non-crystalline allotropic form of silicon. It can be deposited in thin films at low temperatures onto a variety of substrates. It offers some unique capabilities for a variety of electronics.  SONY Vaio VPC-EB4X1E/BQ CPU Fan

Silicon is a fourfold coordinated atom that is normally tetrahedrally bonded to four neighboring silicon atoms. In crystalline silicon (c-Si) this tetrahedral structure continues over a large range, thus forming a well-ordered crystal lattice.

In amorphous silicon this long range order is not present. Rather, the atoms form a continuous random network. HP G62-374CA CPU Fan

Moreover, not all the atoms within amorphous silicon are fourfold coordinated. Due to the disordered nature of the material some atoms have a dangling bond. Physically, these dangling bonds represent defects in the continuous random network and may cause anomalous electrical behavior.

Likewise, the material can be passivated by hydrogen, which bonds to the dangling bonds and can reduce the dangling bond density by several orders of magnitude. HP Pavilion dv5-1203eg CPU Fan

Hydrogenated amorphous silicon (a-Si:H) has a sufficiently low amount of defects to be used within devices such as solar photovoltaic cells, particularly in theprotocrystalline growth regime.[1][2] However, hydrogenation is unfortunately associated with light-induced degradation of the material, termed the Staebler–Wronski effect. HP Pavilion dv7-3131ez CPU Fan

Amorphous alloys of silicon and carbon (amorphous silicon carbide, also hydrogenated, a-Si1-xCx:H) are an interesting variant. Introduction of carbon atoms adds extra degrees of freedom for control of the properties of the material. The film could also be made transparent to visible light.

Increasing concentrations of carbon in the alloy widen the electronic gap between conduction and valence bands (also called "optical gap" and bandgap). Dell Vostro 3450 CPU Fan

This can potentially increase the light efficiency of solar cells made with amorphous silicon carbide layers. On the other hand, the electronic properties as asemiconductor (mainly electron mobility), are adversely affected by the increasing content of carbon in the alloy, due to the increased disorder in the atomic network.

Several studies are found in the scientific literature, mainly investigating the effects of deposition parameters on electronic quality, SONY Vaio VGN-CR23/N CPU Fan

but practical applications of amorphous silicon carbide in commercial devices are still lacking.

While a-Si suffers from lower electronic performance compared to c-Si, it is much more flexible in its applications. For example, a-Si layers can be made thinner than c-Si, which may produce savings on silicon material cost.

One further advantage is that a-Si can be deposited at very low temperatures, e.g., as low as 75 degrees Celsius. HP Pavilion dv6-3043tx CPU Fan

This allows for deposition on not only glass, but plastic as well, making it a candidate for a roll-to-roll processing technique. Once deposited, a-Si can be doped in a fashion similar to c-Si, to form p-type or n-type layers and ultimately to form electronic devices.

Another advantage is that a-Si can be deposited over large areas by PECVD. HP Pavilion dv6-3163eo CPU Fan

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